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新浦京8883平台
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董召文     特聘研究员,博士生导师

研究方向:主族元素化学,燃料化学,计算化学

联系方式:          Email:dongzhaowen@scu.edu.cn

个人主页:点击进入

简历:

学习及工作经历

2022.07至今 新浦京8883平台,特聘研究员, 博士生导师

2019.042022.05 瑞士洛桑联邦理工学院(EPFL,博士后,合作导师:Kay Severin 教授

2019.012019.03德国奥登堡大学,博士后,合作导师:Thomas Müller 教授

2015.072018.12 德国奥登堡大学,博士(Summa Cum Laude拉丁文最高荣誉学位)导师:Thomas Müller教授

2012.092015.06 杭州师范大学有机硅化学及材料教育部重点实验室,硕士,导师:李志芳教授

主要研究方向

低价(低配位)主族元素化合物由于其特殊的电子结构和性质,在小分子活化、催化以及能源材料等领域展现出重要的应用前景。如何高效合成结构新颖且具有高反应活性的低价(低配位)主族元素化合物一直是当代主族元素化学的研究热点和前沿。目前我们课题组的主要研究方向包括:1. 新型低配位p区化合物的合成及应用研究; 2. 新型主族元素掺杂的“芳香性”杂环配体的合成及其性质研究; 3. 新型高能硼燃料的开发和利用。

招生信息:课题组成立于20227月,目前正处于起步发展阶段,常年欢迎对主族元素化学、金属有机化学研究方向感兴趣的本科生、研究生,博士生加入,课题组热烈欢迎优秀的青年博士加入团队,从事博士后研究,与课题组共同成长

课题组优势:你将获得更多与导师讨论课题的机会,并且在导师的指导下开展工作。课题组鼓励学生基于双方共同研究兴趣以及个人未来规划等方面与导师进行探讨。课题组始终秉承将实验与理论相结合的工作理念。我们寻求的“你”,不是在此刻分数的高低,而是“你”对本专业的热忱,信念和所愿为之的持续努力。Not we want you, but we can achieve together!

主要工作业绩

董召文博士近年来一直致力于主族元素化学研究,围绕含硅、锗元素的高反应活性中间体的“精准合成”、“新结构”和“新性质”等科学问题,开展了系统研究。主要贡献包括三个方面:1)开发了一种合成“高反应活性”硅、锗化合物的新方法;2)构建了几种结构新颖的重十四族元素的卡宾类似物,并系统探究了它们在小分子活化领域的应用;3)首次验证了路易斯酸碱反应的单电子转移新机制。目前已在国际著名刊物共计发表SCI论文27篇,其中第一作者论文17篇,包括1Acc. Chem. Res.3J. Am. Chem. Soc.3Angew. Chem. Int. Ed.2Chem. Sci.以及4 Chem. Eur. J.;其中5篇文章被选为封面文章。

主要奖励和荣誉

2023 成都市“蓉漂计划”特聘专家

2023 四川大学优秀科研人才奖

2022 四川省“天府峨眉计划”青年科技人才

2021 四川大学“双百人才工程”B计划

2018 德国奥登堡大学优秀博士论文奖

2017 国家优秀自费留学生奖学金

2015 德国“Georg-Lichtenberg-Promotionsstipendien”博士奖学金

承担项目:

1. 国家重点研发计划青年科学家项目,2023YFC3903200,典型废塑料无金属催化醇解及高纯单体分离与利用技术研究,20232026,在研,子任务负责人

2. 四川省自然科学基金,2023NSFSC1083,稳定自由基光催化剂的设计、合成及其在光催化还原反应中的应用, 20232024,在研,主持

3. 四川大学人才科研启动基金,YJ202269,低价主族元素试剂的开发及其应用, 20222025,在研,主持

4. 新浦京8883平台科研启动基金,低价硅试剂的开发及其应用, 20222025,在研,主持

代表性成果(获奖成果、专著、论文、专利)

SCU:

1. Bastiaan Kooij, Zhaowen Dong, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Kay Severin*, Synthesis and Reactivity of an Anionic Diazoolefin, Angew. Chem. Int. Ed. 2023, 62, e202308625.

2. Paul Varava, Tak Hin Wong, Zhaowen Dong, Anastasia Yu. Gitlina, Andrzej Sienkiewicz, Wolfram Feuerstein, Rosario Scopelliti, Farzaneh Fadaei-Tirani, Kay Severin*, Head-to-Tail Dimerization of N-Heterocyclic Diazoolefins, Angew. Chem. Int. Ed. 2023, 62, e2023033.

Before SCU:

3. Paul Varava; Zhaowen Dong, Rosario Scopelliti, Farzaneh Fadaei-Tirani, Kay Severin*, Isolation and Characterization of Diazoolefins, Nat. Chem. 2021, 13, 1055−1060. (highlighted in Nat. Chem. 2021, 13, 1030–1032)

4. Zhaowen Dong, Jan Mathis Winkler, Marc Schmidtmann, Thomas Müller*, Three-membered Cyclic Digermylenes Stabilized by an N-heterocyclic Carbene, Chem. Sci. 2021, 12, 6287−6292. (featured on the inside cover; selected as 2021 Chemical Science HOT article; highlighted in ChemistryViews)

5. Zhaowen Dong, Lena Albers, Thomas Müller*, Trialkylsilyl-Substituted Silole and Germole D ianions as Precursors for Unusual Silicon and Germanium Compounds, Acc. Chem. Res. 2020, 53, 532−543.

6. Zhaowen Dong, Cristian Pezzato, Andrzej Sienkiewicz, Rosario Scopelliti, Farzaneh Fadaei Tirani, Kay Severin*, SET Processes in Lewis Acid–Base Reactions: The Tritylation of N-Heterocyclic Carbenes, Chem. Sci. 2020, 11, 7615−7618.

7. Zhaowen Dong, Katja Bedbur, Marc Schmidtmann, Thomas Müller*, Hafnocene-based Bicyclo[2.1.1]hexene Germylenes–Formation, Reactivity, and Structural Flexibility, J. Am. Chem. Soc., 2018, 140, 3052−3060.

8. Zhaowen Dong, Hanna H. Cramer, Marc Schmidtmann, Lucas A. Paul, Inke Siewert, Thomas Müller*, Evidence for Single Electron Shift in a Lewis Acid Base Reaction, J. Am. Chem. Soc. 2018, 140, 15419−15424. (featured on the supplementary cover; highlighted in Nachr. Chem.)

9. Zhaowen Dong, Oliver Janka, Jutta Koesters, Marc Schmidtmann, Thomas Müller*, A Dimeric η1, η5-Germole Dianion Bridged Titanium(III) Complex with a Multicenter Ti-Ge-Ge-Ti Bond, Angew. Chem. Int. Ed. 2018, 57, 8634−8638.

10. Patrik. Tholen, Zhaowen Dong, Marc Schmidtmann, Lena Albers, Thomas. Müller*, A Neutral η5-Aminoborole Complex of Germanium(II), Angew. Chem. Int. Ed. 2018, 57, 13319–13324.

11. Zhaowen Dong, Crispin R. W. Reinhold, Marc Schmidtmann, Thomas Müller*, A Stable Silylene with a σ2, π-Butadiene Ligand, J. Am. Chem. Soc. 2017, 139, 7117−7123.

12. Zhaowen Dong, Crispin R. W. Reinhold, Marc Schmidtmann, Thomas Müller*, A Germylene Stabilized by Homoconjugation, Angew. Chem. Int. Ed. 2016, 55, 15899−15904.

13. Xu-Qiong Xiao#, Zhaowen Dong# (co-first author), Zhifang Li*, Chenting Yan, Guoqiao Lai, Mitsuo Kira*, 1,3-D iazasilabicyclo[1.1.0]butane with a Long Bridging N-N Bond, Angew. Chem. Int. Ed. 2016, 55, 3758−3762.

14. Zhaowen Dong*, Andrzej Sienkiewicz, Abdusalom A. Suleymanov, Cesare Berton, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Kay Severin*, A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion, Chem. Eur. J. 2022, 28, e20220089.

15. Zhaowen Dong, J. Terence Blaskovits, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Andrzej Sienkiewicz, Clémence Corminboeuf*, Kay Severin*, Tuning the π-Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study, Chem. Eur. J. 2021, 27, 11983-11988.

16. Zhaowen Dong, Marc Schmidtmann, Thomas Müller*, Potassium Salts of 2,5‐Bis(trimethylsily l)‐Germolide: Switching between Aromatic and Non‐Aromatic States, Chem. Eur. J. 2019, 25, 10858−10865. (selected as hot paper and featured on the front cover)

17. Zhaowen Dong, Lena Albers, Marc Schmidtmann, Thomas Müller*, A Germacalicene: Synthesis, Structure, and Reactivity, Chem. Eur. J. 2019, 25, 1098−1105. (selected as hot paper)

18. Zhaowen Dong, Crispin R. W. Reinhold, Marc Schmidtmann, Thomas Müller*, Trialkylsilyl-Substituted Silole and Germole Dianions, Organometallics 2018, 37, 4736−4743.

19. Zhaowen Dong, Zhifang Li*, Xupeng Liu, Chenting Yan, Ningka Wei, Mitsuo Kira*, Thomas Müller*, Dihydrogen Splitting Using Dialkylsilylene-Based Frustrated Lewis Pairs, Chem. Asian J. 2017, 12, 1204−1207. (special issue on advances in silicon chemistry and featured on the back cover)

20. Zhaowen Dong, Marc Schmidtmann, Thomas Müller*, Reactivity of a Bicyclo[2.1.1]hexene Germylene towards Elemental Chalcogens, Z. Anorg. Allg. Chem. 2018, 644, 1041–1046.

21. Zhaowen Dong, Xuqiong Xiao, Zhifang Li*, Qiong Lu, Guoqiao Lai, Mitsuo Kira*, Elusive 2H-1,2-Oxasiletes Through Reactions of an Isolable Dialkylsilylene with Diazocarbonyl Compounds, Org. Biomol. Chem. 2015, 13, 94719476.

22. Bastiaan Kooij, Zhaowen Dong, Paul Varava, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Laura Piveteau and Kay Severin*, Vanadium Complexes with N-Heterocyclic Vinylidene Ligands, Chem. Commun., 2022, 58, 4204–4207.

23. Hong Zhang, Felix Thomas Eickemeyer, ……. Zhaowen Dong, Jovana V. Milić*, Michael Grätzel*, Multimodal Host–Guest Complexation for Efficient and Stable Perovskite Photovoltaics, Nat. Commun. 2021, 12, 3383–3393.

24. Shaofeng Pang,* Fangfang Liu, Yujing Zhang, Zhaowen Dong, Qiong Su, Wenfang Wang, Zhenhua Li, Feng Zhou, and Yanbin Wang*, Construction of Functional Superhydrophobic Biochars as Hydrogen Transfer Catalysts for Dehydrogenation of N-Heterocycles, ACS Sustainable Chem. Eng. 2021, 9, 9062–9077.

25. Abdusalom A. Suleymanov, Eliott Le Du, Zhaowen Dong, Bastian Muriel, Rosario Scopelliti, Farzaneh Fadaei-Tirani, Jeróme Waser,* and Kay Severin*, Triazene-Activated Donor–Acceptor Cyclopropanes: Ring-Opening and (3+2) Annulation Reactions, Org. Lett. 2020, 11, 45174522.

26. Crispin R. W. Reinhold, Zhaowen Dong, Jan M. Winkler, Henning Steinert, Marc Schmidtmann, and Thomas Meller*, A One-Step Germole to Silole Transformation and a Stable Isomer of a Disilabenzene, Chem. Eur. J. 2018, 24, 848−854.

27. Xupeng Liu, Xuqiong Xiao, Zheng Xu, Xiuming Yang, Zhifang Li*, Zhaowen Dong, Chengting Yan, Guoqiao Lai, Mitsuo Kira*, Reactions of an Isolable Dialkylsilylene with Carbon Dioxide and Related Heterocumulenes, Organometallics 2014, 33, 5434−5439.

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