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余达刚     教授、博士生导师

研究方向:二氧化碳利用、自由基化学(可见光化学、电化学)、廉价金属催化

联系方式:028-85470816          Email:yudagang86@163.com (优先) dgyu@scu.edu.cn

个人主页:点击进入

简历:

余达刚博士,男,19869月出生于江西奉新。

学习经历

2003.09—2007.07 新浦京8883平台读本科,导师:冯小明教授,袁立华教授

2007.09—2012.07北京大学化学与分子工程学院有机化学专业攻读博士学位,导师:施章杰教授

工作经历

2012.10—2014.12  德国明斯特大学进行博士后研究,洪堡学者,导师: Prof. Frank Glorius

2015.01至今     新浦京8883平台从事教学和科研,教授, 博士生导师

学术兼职

Chemical Synthesis编委(CO2化学和有机化学领域编辑)

《中国化学快报》高级编委

《化学学报》、《有机化学》、Asian J. Org. Chem编委

Sci. Bull. 和《科学通报》、Sci. China Chem.《中国科学-化学》、Chin. J. Catal.青年编委

Tetrahedron Green Chem, Advisory Board Member

中国化学会二氧化碳化学专业委员会委员

中国化学会光化学专业委员会委员

中国化学会催化委员会均相催化专业委员会委员

中国化学会青年化学工作者委员会第三届委员

中国感光学会第一届青年理事会理事

主要研究方向

绿色有机合成化学(二氧化碳利用、可见光催化、电化学)

过渡金属催化方法学(铜、铁等廉价金属催化)

功能分子构建新方法研究(重要杂环、羧酸合成)

诚招副研究员、博后、研究助理、硕博生以及交流生

主要工作业绩

二氧化碳(CO2)作为空气中的重要组分,也是广泛存在、廉价易得、无毒、稳定、可再生循环使用的碳一C1)资源。由于CO2在热力学和动力学方面有较高的稳定性,反应活性较低,CO2活化具有巨大的挑战。2015年余达刚博士独立建组以来,坚持围绕CO2活化与转化的基本科学问题开展独特研究,发展了CO2高效活化与选择性转化的新理念、新策略和新反应,具体如下:

针对碳氢键氧化羰基化反应中存在的问题(需要使用剧毒的CO和当量的氧化剂),我们首次提出“CO2 = CO + [O]”理念,利用CO2代替CO和氧化剂参与碳氢键羰基化反应,发展了近十类重要含羰基杂环类化合物的高效合成方法,提出了新反应机制,不仅变废为宝,还降低成本,提高安全性,具有较强的实用性;基于过渡金属催化和可见光催化策略,我们发展了自由基型CO2转化模式,一方面通过调控自由基参与不饱和烃转化反应的选择性,在室温常压下实现了噁唑啉酮和多种类型羧酸的高效制备,另一方面基于可见光促进单电子活化策略和电还原策略,通过单电子还原CO2或底物形成自由基负离子,实现了具有独特区域选择性的烯烃羧基化反应以及氮杂芳烃区域选择性可调控的羧基化反应;基于极性翻转策略,我们通过惰性化学键(如碳氟键、碳氮键和碳氧键)的选择性断裂实现了CO2参与的羧基化反应;此外,我们实现了铜或镍催化CO2参与的不饱和烃的碳碳成键反应,取得了优秀的对映选择性、化学选择性、区域选择性和Z/E选择性,高效构建了具有手性(季碳)中心的高苄醇高烯丙醇和羧酸。这些工作实现了CO2的变废为宝和高附加值产品的精准合成,为研究CO2活化的本质和规律提供了新的实验基础和理论模型,为促进我国CO2化学研究起了积极的作用。

独立工作以来,余达刚博士以通讯作者身份在NatureNature Catal.Nature Synth.Acc. Chem. Res.Chem.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Nature Commun.Sci. Bull.Chin. J. Catal.CCS Chem. Sci. China Chem.Chin. Chem. Lett.Chin. J. Chem.等学术刊物上发表学术论文90篇,其中有多篇论文成为相应期刊封面、扉页文章、VIP和当月下载量前列的文章,多篇被国家自然科学基金委、科学网、中国网、ChemistryViewsSynformSynfactsOrganic Chemistry PortalOPR&D和《有机化学》等作为亮点介绍。此外,在国内外学术会议、大学和企业做了130余次报告作为共同客座编辑组织了Chin. J. Chem.Green Chem.Chin. J. Catal.二氧化碳化学专辑。    

主要奖励和荣誉  

2023年四川大学十大基础研究进展奖

2023年四川大学优秀本科毕业论文指导教师

2022年国家自然科学基金委杰出青年基金

2022 Kyoto Rising-Star Lectureship Award

2022年四川省学术和技术带头人

2021年中国催化新秀奖

2021年川渝科学技术大会优秀学术论文一等奖

2021年四川大学先进个人、四川大学百人计划A

2021大学生创新创业教育优秀指导教师、四川大学拔尖创新人才优秀指导教师、四川大学优秀社团指导教师

2020“Science China Chemistry” Emerging Investigator

2020“Chemical Communications” Emerging Investigator

2020 四川大学中青年科技领军人才培育计划

2019年四川大学优秀本科毕业论文指导教师、四川大学拔尖创新人才培养优秀指导教师、四川大学大学生创新创业教育优秀指导教师、四川大学课堂教学质量优秀奖

2018年中国化学会青年化学奖

2018年国家自然科学基金委优秀青年基金

2018年霍英东青年教师基金

2018年四川大学优秀教师、四川大学优秀青年科技人才奖

2017 ACP Lectureship Awards to Japan

2017 Thieme Chemistry Journal Award

2017年四川大学优秀本科毕业论文指导教师、四川大学拔尖创新人才优秀指导教师、四川大学大学生创新创业教育优秀指导教师

2016Organic Chemistry Frontiers” Emerging Investigator

2016年四川大学青年科技人才奖、四川大学优秀本科毕业论文指导教师

2014年海外高层次人才引进计划青年项目

2013-2014年德国洪堡奖学金

2013Reaxys PhD Prize (Finalist)

2012年陶氏化学可持续发展创新奖(特等奖)

2012年北京大学学术十杰、北京大学化学与分子工程学院优秀博士论文

2011SciFinder Recognition in Excellence Program for OMCOS16

2011年北京大学化学与分子工程学院化学之星二等奖

2010年北京大学三好学生、北京大学常青特等奖学金”    

2009年北京大学常青一等奖学金”      

代表性成果 (获奖成果、专著、论文、专利)

1. Y.-Y. Gui,*,† X.-W. Chen, X.-Y. Mo, J.-P. Yue, R. Yuan, Y. Liu, L.-L. Liao, J.-H. Ye, D.-G. Yu*, Cu-Catalyzed Asymmetric Dicarboxylation of 1,3-Dienes with CO2. J. Am. Chem. Soc. 2024, 146, DOI: 10.1021/jacs.3c14146.

2. Y.-X. Jiang, L.-L. Liao, T.-Y. Gao, W.-H. Xu, W. Zhang, L. Song, G.-Q. Sun, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(sp⟡)-H bonds using CO2. Nat. Synth. 2024, DOI : 10.1038/s44160-023-00465-6. (Equal contribution. Highlighted by化学加、CBG、化学深耕堂、催化计、化学宝库、有趣的化学合成)

3. B. Yu, Y. Liu, H.-Z. Xiao, S.-R. Zhang, C.-K. Ran, L. Song, Y.-X. Jiang, C.-F. Li, J.-H. Ye,* D.-G. Yu*, Switchable Divergent Di- or Tricarboxylation of Allylic Alcohols with CO2. Chem 2024, https://doi.org/10.1016/j.chempr.2023.12.005. (Highlighted by科学网、化学加、CBG、化学深耕堂、催化计、化学宝库、有趣的化学合成)

4. K.-G. Cao, T.-Y. Gao, L.-L. Liao,* C.-K. Ran, Y.-X. Jiang, W. Zhang, Q. Zhou, J.-H. Ye, Y. Lan, D.-G. Yu*, Photocatalytic carboxylation of styrenes with CO2 via C=C double bond cleavage. Chin. J. Catal. 2024, 56, 74-80 (Equal contribution)

5. T.-Y. Gao, X.-Y. Mo, S.-R. Zhang, Y.-X. Jiang, S.-P. Luo, J.-H. Ye,* D.-G. Yu*, Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO2. Chin. Chem. Lett. 2024, https://doi.org/10.1016/j.cclet.2023.109364 

6. Y. Liu, Z.-H. Wang, L. Yuan , Y. Li, D.-G. Yu, J.-H. Ye*, Photocatalytic Dicarboxylation of Strained C–C Bonds with CO2 via Consecutive Visible-Light-Induced Electron Transfer. Chin. Chem. Lett. 2024, 34, https://doi.org/10.1016/j.cclet.2023.109138 (Equal contribution)

7. G.-Q. Sun, P. Yu, W. Zhang, W. Zhang, Y. Wang, L.-L. Liao, Z. Zhang, L. Li, Z. Lu, D.-G. Yu*, S. Lin* Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations. Nature 2023, 615, 67 (Equal contribution. Highlighted by 中国网、基金委、ScienceDaily, EurekAlert, Chem, Chem. Syn., Chin. Sci. Bull., Chin. Chem. Lett.X-MOL、化学加、能源学报、四川大学主页)

8. J.-P. Yue, J.-C. Xu, H.-T. Luo, X.-W. Chen, H.-X. Song, Y. Deng, L. Yuan, J.-H. Ye*, D.-G. Yu*, Metallaphotoredox-enabled aminocarboxylation of alkenes with CO2. Nat. Catal. 2023, 6, 959–968.Highlighted by Sci. China Chem.Synfacts 2024, 20, 0058研之成理、催化+、化学加、今日新材料、四川大学主页).

9. W. Zhang, D.-G. Yu*, J.-H. Ye*, Photocatalytic Activation of Water: An Unique Way to Mimic Free Hydrogen Atom for Efficient Hydrogenation. Chem 2023, 9, 2375-2377 (Highlight)

 

10. S.-Y. Min, H.-X. Song, S.-S. Yan*, R. Yuan, J.-H. Ye, B.-Q. Wang, Y.-Y. Gui*, D.-G. Yu*, Photocatalytic Defluorocarboxylation Using Formate Salts as Both Reductant and Carbon Dioxide Source. Green Chem. 2023, 25, 6194-6199.

Graphical abstract: Photocatalytic defluorocarboxylation using formate salts as both a reductant and a carbon dioxide source

11. W. Zhang, Z. Chen, Y.-X. Jiang, L.-L. Liao, W. Wang, J.-H. Ye*, D.-G. Yu*, Arylcarboxylation of unactivated alkenes with CO2 via visible-light photoredox catalysis. Nat. Commun. 2023, 14, 3529.

12. W. Zhang, L.-L. Liao, L. Li, Y. Liu, L.-F. Dai, G.-Q. Sun, C.-K. Ran, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2. Angew. Chem. Int. Ed. 2023, 62, e202301892. (Equal contribution)

13. L. Chen, Q. Qu, C.-K. Ran, W. Wang, W. Zhang, Y. He, L.-L. Liao, J.-H. Ye*, D.-G. Yu*, Photocatalytic Carboxylation of C−N Bonds in Cyclic Amines with CO2 by Consecutive Visible-Light-Induced Electron Transfer. Angew. Chem. Int. Ed. 2023, 62, 202217918. (Highlighted by Synfacts 2023, 19, 0527)

14. H.-Z. Xiao,B. Yu, S.-S. Yan , W. Zhang , X.-X. Li, Y. Bao, S.-P. Luo, J.-H. Ye*, D.-G. Yu*, Photocatalytic 1,3-Dicarboxylation of Unactivated Alkenes with CO2. Chin. J. Catal. 2023, 50, 222 (Equal contribution)

15. M. Miao, L. Zhu, H. Zhao, L. Song, S.-S. Yan, L.-L. Liao, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Visible-light-driven thio-carboxylation of alkynes with CO2: facile synthesis of thiochromones. Sci. China Chem. 2023, 66, 1457.

16. Y.-Y. Gui, X.-W. Chen, D.-G. Yu*, Teaching an old N-alkylation new tricks: from SN1 and SN2 N-alkylation to radical enantioconvergent N-alkylation. Sci. Bull. 2023, 68, 1225 (Equal contribution)

17. C.-K. Ran, H.-Z. Xiao, L.-L. Liao,* T. Ju, W. Zhang, D.-G. Yu*, The progress and challenges in dicarboxylation with CO2. Natl. Sci. Open 2023, 2, 20220024.

18. Q. Qu, L. Chen, Y. Deng, Y.-Y. Gui*, D.-G. Yu*, Visible-Light Photocatalytic Barbier-Type Reaction of Aziridines and Azetidines with Unactivated Aldehydes. Synlett 2023, 34, 1385-1390 (Equal contribution)

19. K. Ren, R. Yuan, Y.-Y. Gui*, X.-W. Chen, S.-Y. Min, B.-Q. Wang, D.-G. Yu*, Cu-Catalyzed Reductive Aminomethylation of 1,3-Dienes with N,O-acetals: Facile Construction of β-Chiral Amines with Quaternary Stereocenters. Org. Chem. Front. 2023, 10, 467. (Equal contribution).

20. L. Song, W. Wang, J.-P. Yue, Y.-X. Jiang, M.-K. Wei, H.-P. Zhang, S.-S. Yan, L.-L. Liao, D.-G. Yu*, Visible-Light Photocatalytic Di- and Hydro-Carboxylation of Unactivated Alkenes with CO2. Nat. Catal. 2022, 5, 832 (Equal contribution)

21. C.-K. Ran, D.-G. Yu*, Ready and label. Nat. Chem. Rev. 2022, 6, 679 (News & Views)

22. W.-J. Zhou, C.-K. Ran, D.-G. Yu*, 硼自由基助力苄基C-OH键羧基化。有机化学 2022, 42, 2599.

23. Z. Zhang, Y. Deng, Q.-F. Zhang*, D.-G. Yu*, 可见光促进二氧化碳参与的羧基化反应 高等学校化学学报2022, 43, 20220255.

24. Z.-Y. Bo, S.-S. Yan, T.-Y. Gao, L. Song, C.-K. Ran, Y. He, W. Zhang*, G.-M. Cao, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Selective Carboxylation of C(sp2)−F Bonds in Polyfluoroarenes with CO2. Chin. J. Catal. 2022, 43, 2388-2394. (Equal contribution)

25. Y. Huang,* D.-G. Yu*, G. Wang,* Preface to special column on catalytic conversion of CO2. Chin. J. Catal. 2022, 43, 1545-1546. (Editorial)

26. L.-L. Liao, L. Song, S.-S. Yan, J.-H. Ye,* D.-G. Yu*, Highly reductive photocatalytic systems in organic synthesis. Trend. Chem. 2022, 4, 512-527.

27. L.-L. Liao, Z.-H. Wang, K.-G. Cao, G.-Q. Sun, W. Zhang, C.-K. Ran, Y. Li, L. Chen, G.-M. Cao, D.-G. Yu*, Electrochemical Ring-Opening Dicarboxylation of Strained Carbon-Carbon Single Bonds with CO2: Facile Synthesis of Diacids and Derivatization into Polyesters. J. Am. Chem. Soc. 2022, 144, 2062.

28. C.-K. Ran, Y.-N. Niu, L. Song, M.-K. Wei, Y.-F. Cao, S.-P. Luo, Y.-M. Yu, L.-L. Liao,* D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Activated C(sp3)─O bonds with CO2. ACS Catal. 2022, 12, 18. (Equal contribution. Top 1 of the most read articles in ACS Catal. in December 2021 )

29. K. Jing, M.-K. Wei, S.-S. Yan, L.-L. Liao, Y.-N. Niu, S.-P. Luo, B. Yu*, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Benzyl Halides with CO2: Mild and Transition-Metal-Free. Chin. J. Catal. 2022, 43, 1667. (Invited contribution for "Catalytic Conversion of CO2")

30. X.-Y. Zhou, X.-Y. Li, Z. Zhang*, D.-G. Yu*, Thiocarbonylation of C(sp3)-H bonds in pyridylamines with CS2: Facile synthesis of pyrido[1,2-a]pyrimidine-4-thiones. Chin. Chem. Lett. 2021, 32, 4015..

31. G.-Q. Sun, W. Zhang, L.-L. Liao, L. Li, Z.-H. Nie, J.-G. Wu, Z. Zhang, D.-G. Yu*,  Nickel-Catalyzed Electrochemical Carboxylation of Unactivated Aryl and Alkyl Halides with CO2. Nat. Commun. 2021, 12, 7086.

32. J. Liu, H.-Z. Xiao, Q. Fu,* D.-G. Yu*, Advances in Radical Phosphorylation from 2016 to 2021. Chem. Syn. 2021, 1, 9 (Equal contribution. Invited contribution)

33. S.-S. Yan, S.-H. Liu, L. Chen, Z.-Y. Bo, K. Jing, T.-Y. Gao, B. Yu, Y. Lan,* S.-P. Luo, D.-G. Yu*, Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2. Chem 2021, 7, 3099.

34. X.-Y. Zhu, C.-K. Ran, M. Wen, G.-L. Guo, Y. Liu, L.-L. Liao, Y.-Z. Li,* M.-L. Li, D.-G. Yu*, Prediction of multicomponent reaction yields using machine learning. Chin. J. Chem. 2021, 39, 3231 (Equal contribution)

图片1

35. C.-K. Ran, L.-L. Liao, T.-Y. Gao, Y.-Y. Gui*, D.-G. Yu*, Recent progress and challenges in carboxylation with CO2. Cur. Opin. Green Sustain. Chem. 2021, 32, 100525 (Equal contribution)

36. D.-G. Yu*, L.-N. He*, Introduction to CO2 utilisation. Green Chem. 2021, 23, 3499. (Editorial)

37. J.-H. Ye, T. Ju, H. Huang, L.-L. Liao, D.-G. Yu*, Radical Carboxylative Cyclizations and Carboxylations with CO2. Acc. Chem. Res. 2021, 54, 2518.

38. T. Ju, Y.-Q. Zhou, K.-G. Cao, Q. Fu, J.-H. Ye, G.-Q. Sun, X.-F. Liu, L. Chen, L.-L. Liao, D.-G. Yu*, Dicarboxylation of alkenes, allenes, and (hetero)arenes with CO2 via visible-light photoredox catalysis. Nat. Catal. 2021, 4, 304–311.

39. G.-M. Cao, X.-L. Hu, L.-L. Liao, S.-S. Yan, L. Song, J. J. Chruma, L. Gong, D.-G. Yu*, Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2. Nat. Commun. 2021, 12, 3306

.

40. Y.-N. Niu, X.-H. Jin, L.-L. Liao, H. Huang, B. Yu, Y.-M. Yu*, D.-G. Yu*, Visible-Light-Driven External-Photocatalyst-Free Alkylative Carboxylation of Alkenes with CO2. Sci. China Chem. 2021, 64, 1164

41. X.-W. Chen, J.-P. Yue, K. Wang, Y.-Y. Gui, Y.-N. Niu, J. Liu, C.-K. Ran, W. Kong,* W.-J. Zhou, D.-G. Yu*, Nickel-Catalyzed Asymmetric Reductive Carbo-Carboxylation of Alkenes with CO2. Angew. Chem. Int. Ed. 2021, 60, 14068 (Highlighted by WielyChem, X-Mol, CBG).

42. L.-L. Liao, G.-M. Cao, Y.-X. Jiang, X.-H. Jin, X.-L. Hu, J. J. Chruma, G.-Q. Sun, Y.-Y. Gui, D.-G. Yu*, α-Amino Acids and Peptides as Bifunctional Reagents: Carbo-Carboxylation of Activated Alkenes via Recycling CO2. J. Am. Chem. Soc. 2021, 143, 2812 (One of the most read JACS papers in March, 2021. Highlighted by Synfacts, Chin. J. Org. Chem., CBG, X-Mol and WeeChem)

43. Y.-M. Jiang, J. Liu, Q. Fu,* Y.-M. Yu,* D.-G. Yu*, Visible-Light-Driven Phosphonoalkylation of Alkenes. Synlett 2021, 32, 378 (Equal contribution. Invited contribution for "Radicals by Young Chinese Organic Chemists")

44. C.-K. Ran, L. Song, Y.-N. Niu, M.-K. Wei, Z. Zhang,* X.-Y. Zhou, D.-G. Yu*, Transition-metal-free synthesis of thiazolidin-2-ones and 1,3-thiazinan-2-ones from arylamines, elemental sulfur and CO2. Green Chem. 2021, 23, 274 (Invited for Special Issue: CO2 Utilization. Highlighted by Chem-station and RSC China)

45. Y.-X. Jiang, L. Chen, C.-K. Ran, L. Song, W. Zhang,* L.-L. Liao, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Ring-Opening Carboxylation of Cyclic Oxime Esters with CO2. ChemSusChem 2020, 13, 6312. (Invited for Special Issue: Green Carbon Science-CO2 Capture and Conversion)

46. Z. Zhang, J.-H. Ye, T. Ju, L.-L. Liao, H. Huang, Y.-Y. Gui, W.-J. Zhou,* D.-G. Yu*, Visible Light-Driven Catalytic Reductive Carboxylation with CO2. ACS Catal. 2020, 10, 10871. (Equal contribution. Perspective)

47. L. Song, D.-M. Fu, L. Chen, Y.-X. Jiang, J.-H. Ye, L. Zhu, Y. Lan,* Q. Fu, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Remote Difunctionalizing Carboxylation of Unactivated Alkenes with CO2. Angew. Chem. Int. Ed. 2020, 59, 21121. (Hot Paper. Highlighted by Synfacts 2020, 16, 1372; Chin. J. Org. Chem2020, 40, 4375; WielyChem).

48. H. Huang, J.-H. Ye, L. Zhu, C.-K. Ran, M. Miao, W. Wang, H. Chen, W.-J. Zhou, Y. Lan,* B. Yu, D.-G. Yu*, Visible Light-Driven Anti-Markovnikov Hydrocarboxylation of Acrylates and Styrenes with CO2. CCS Chem. 2020, 2, 1746  (Equal contribution.)

49. W.-J. Zhou,* X.-D. Wu, M. Miao, Z.-H. Wang, L. Chen, S.-Y. Shan, G.-M. Cao, D.-G. Yu*,  Light Runs Across Iron Catalysts in Organic Transformations. Chem. Eur. J. 2020, 26, 15052. (Equal contribution. Invited Concept)

50. W.-J. Zhou, Z.-H. Wang, L.-L. Liao, Y.-X. Jiang, K.-G. Cao, T. Ju, Y. Li, G.-M. Cao, D.-G. Yu*, Reductive Dearomative Arylcarboxylation of Indoles with CO2 via Visible-Light Photoredox Catalysis. Nat. Commun. 2020, 11, 3263. (Equal contribution)

51. C.-K. Ran, X.-W. Chen, Y.-Y. Gui*, J. Liu, L. Song, K. Ren, D.-G. Yu*, Recent Advances in Asymmetric Synthesis with CO2. Sci. China Chem. 2020, 63, 1336. (Equal contribution. Sci. China Chem. Emerging Investigators themed collection)

52. 周文俊*蒋元旭陈亮,刘开兴,余达刚*可见光与钯协同催化的有机合成化学。有机化学202040, 3697应邀综述.Equal contribution

53. L. Song, Y.-X. Jiang, Z. Zhang,* Y.-Y. Gui, X.-Y. Zhou, D.-G. Yu*, CO2 = CO + [O]: recent advances in carbonylation of C–H bonds with CO2. Chem. Commun. 2020, 56, 8355 (ChemComm Emerging Investigators themed collection)

54. Z. Zhang,* X.-Y. Zhou, J.-G. Wu, L. Song, D.-G. Yu*, Transition-Metal-Free Lactamization of C(sp3)—H Bonds with CO2: Facile Generation of Pyrido[1,2-a]pyrimidin-4-ones. Green Chem. 2020, 22, 28. (Equal contribution)

55. C.-K. Ran, H. Huang, X.-H. Li, W. Wang, J.-H. Ye, S.-S. Yan, B.-Q. Wang, C. Feng,* D.-G. Yu*, Cu-Catalyzed Selective Oxy-Cyanoalkylation of Allylamines with Cycloketone Oxime Esters and CO2. Chin. J. Chem. 2020, 38, 69 (Invited paper)

56. X.-W. Chen, L. Zhu, Y.-Y. Gui, K. Jing, Y.-X. Jiang, Z.-Y. Bo, Y. Lan,* J. Li, D.-G. Yu*, Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2. J. Am. Chem. Soc. 2019, 141, 18825. (Highlighted by ChemBeanGo and Chin. J. Org. Chem. 2020, 40, 247)

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57. M. Miao, L.-L. Liao, G.-M. Cao, W.-J. Zhou,* D.-G. Yu*, Visible-light-mediated external-reductant-free reductive cross coupling of benzylammonium salts with (hetero)aryl nitriles. Sci. China Chem. 2019, 62, 1519. (Invited Contribution to SPECIAL ISSUE: Organic Free Radical Chemistry)

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58. Z. Zhang, L. Gong, X.-Y. Zhou, S.-S. Yan, J. Li*, D.-G. Yu*, Radical-Type Difunctionalization of Alkenes with CO2. Acta Chim. Sinica 2019, 77, 783 (Invited Contribution to SPECIAL ISSUE: Organic Radical Chemistry)

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59. Q. Fu, Z.-Y. Bo, J.-H. Ye, T. Ju, H. Huang, L.-L. Liao, D.-G. Yu*, Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis. Nat. Commun. 2019, 10, 3592.

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60. S.-S. Yan, D.-S. Wu, J.-H. Ye, L. Gong, X. Zeng, C.-K. Ran, Y.-Y. Gui, J. Li, D.-G. Yu*, Copper-Catalyzed Carboxylation of CF Bonds with CO2. ACS Catal. 2019, 9, 6987. (Highlighted by Synfacts 2019, 15, 1159)

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61. W.-J. Zhou,* G.-M. Cao, Z.-P. Zhang, and D.-G. Yu*, Visible Light-Induced Palladium-Catalysis in Organic Synthesis. Chem. Lett. 2019, 48, 181. (Invited Contribution. Cover)

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62. Y. Chen*, L.-Q. Lu*, D.-G. Yu*, C.-J. Zhu* and W.-J. Xiao*, Visible light-driven organic photochemical synthesis in China. Sci. China Chem. 2019, 62, 24. (Invited Contribution)

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63. L.-L. Liao, G.-M. Cao, J.-H. Ye, G.-Q. Sun, W.-J. Zhou, Y.-Y. Gui, S.-S. Yan, G. Shen, D.-G. Yu*, Visible-light-Driven External-Reductant-Free Cross-Electrophile Couplings of Tetraalkyl Ammonium Salts. J. Am. Chem. Soc. 2018, 140, 17338. (Top 1 most read JACS papers in December, 2018.)

64. T. Ju, Q. Fu, J.-H. Ye, Z. Zhang, L.-L. Liao, S.-S. Yan, X.-Y. Tian, S.-P. Luo, J. Li, D.-G. Yu*, Selective and Catalytic Hydrocarboxylation of Enamides and Imines with CO2 to Generate α,α-Disubstituted α-Amino Acids. Angew. Chem. Int. Ed. 2018, 57, 13897.

65. S.-S. Yan, Q. Fu, L.-L. Liao, G.-Q. Sun, J.-H. Ye, L. Gong, Y.-Z. Bo-Xue, D.-G. Yu*, Transition metal-catalyzed carboxylation of unsaturated substrates with CO2. Coord. Chem. Rev. 2018, 374, 439. (Invited Contribution)

66. W.-J. Zhou,* Yi-Han Zhang, Y.-Y. Gui, L. Sun, D.-G. Yu*, Merging Transition Metal-Catalysis with Photoredox Catalysis: A Environmentally Friendly Strategy for C-H Functionalization. Synthesis 2018, 50, 3359. (Equal contribution. Invited Contribution to the Special Issue on “Photocatalysis”)

67. L. Song, L. Zhu, Z. Zhang, J.-H. Ye, S.-S. Yan, J.-L. Han, Z.-B. Yin, Y. Lan*, D.-G. Yu*, Catalytic Lactonization of Unactivated Aryl C─H Bonds with CO2: Experimental and Computational Investigation. Org. Lett. 2018, 20, 3776. (Top 14 most read papers in July, 2018)

68. Z. Zhang,*J.-H. Ye,D.-S. Wu, Y.-Q. Zhou, D.-G. Yu*, Synthesis of Oxazolidin-2-ones from Unsaturated Amines with CO2 via Homogeneous Catalysis. Chem. Asian J. 2018, 13, 2292. (Equal contribution. Invited Contribution to the Special Issue on “Homogeneous Catalysis from Young Investigators in Asia”)

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69. L. Song, G.-M. Cao, W.-J. Zhou, J.-H. Ye, Z. Zhang, X.-Y. Tian, J. Li, D.-G. Yu*, Pd-catalyzed carbonylation of aryl C─H bonds in benzamides with CO2. Org. Chem. Front. 2018, 5, 2086. (Invited Contribution to the Special Issue on “Celebrating the 90th birthday of Professor Lu Xiyan”)

70. G. Shen, W.-J. Zhou*, X.-B. Zhang, G.-M. Cao, Z. Zhang, J.-H. Ye, L.-L. Liao, J. Li, D.-G. Yu*, Synthesis of tetronic acids from propargylic alcohols and CO2. Chem. Commun. 2018, 54, 5610.

71. S.-S. Yan, L. Zhu, J.-H. Ye, Z. Zhang, H. Huang, H. Zeng, C.-J. Li*, Y. Lan*, D.-G. Yu*, Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2. Chem. Sci. 2018, 9, 4873. (Highlighted by CBG.)

72. L. Sun, J.-H. Ye, W.-J. Zhou*, X. Zeng, D.-G. Yu*, Oxy-Alkylation of Allylamines with Unactivated Alkyl Bromides and CO2 via Visible-Light-Driven Palladium Catalysis. Org. Lett. 2018, 20, 3049. (Top 8 most read papers in May, 2018. Highlighted by CBG.)

73. Z. Zhang*, C.-J. Zhu, M. Miao, J.-L. Han, T. Ju, L. Song, J.-H. Ye, J. Li, D.-G. Yu*, Lactonization of C(sp2)─H Bonds in Enamides with CO2. Chin. J. Chem. 2018, 36, 430. (Cover. Invited Contribution to the Special Issue on “CO2 chemistry”)

74. Z.-B. Yin, J.-H. Ye, W.-J. Zhou, Y.-H. Zhang, L. Ding, Y.-Y. Gui, S.-S. Yan, J. Li, D.-G. Yu*, Oxy-Difluoroalkylation of Allylamines with CO2 via Visible-Light Photoredox Catalysis. Org. Lett. 2018, 20, 190. (Equal contribution. ESI高被引论文)

75. Y.-Y. Gui, Z.-X. Wang, W.-J. Zhou*, L.-L. Liao, L. Song, Z.-B. Yin, J. Li, D.-G. Yu*, Arylation of Aniline C(sp3)─H Bonds with Phenols by an in-situ Activation Strategy. Asian J. Org. Chem. 2018, 7, 537. (Selected as Cover and VIP. Highlighted by ChemistryViews. Invited paper for the Special Issue on Early Career Researchers in China)

76. L. Zhu, J.-H. Ye, M. Duan, X. Qi, D.-G. Yu*, R. Bai*, Y. Lan*, On the Mechanism of Copper-Catalyzed Oxytrifluoromethylationof Allylamines with CO2: A Computational Study.  Org. Chem. Front. 2018, 5, 633. (ESI高被引论文)

77. X. Yan, H. Sun, H. Xiang, D.-G. Yu, D. Luo, X. Zhou,* Palladium-Catalyzed C(carbonyl) –C Bond Cleavage of Amides: A Facile Access to Phenylcarbamate Derivatives with Alcohols. Chem. Commun. 2018, 54, 8606.

78. Y.-Y. Gui, N. Hu, X.-W. Chen, L.-L. Liao, T. Ju, J.-H. Ye, Z. Zhang, J. Li, D.-G. Yu*, Highly Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of Styrenes and 1,3-Dienes with CO2. J. Am. Chem. Soc. 2017, 139, 17011. (Equal contribution. Cover. Top 4 most read JACS papers in November, 2017. Highlighted by Synfacts 2018, 14, 0177, CJOC, X-MOL, OPR&D and Organic Chemistry Portal)

79. J.-H. Ye, M. Miao, H. Huang, S.-S. Yan, Z.-B. Yin, W.-J. Zhou, D.-G. Yu*, Visible light-driven and Iron-promoted Thiocarboxylation of Styrenes and Acrylates with CO2. Angew. Chem. Int. Ed. 2017, 56, 15416. (Top 11 most accessed papers in November, 2017. Highlighted by X-MOL)

80. W.-J. Zhou, G.-M. Cao, G. Shen, X.-Y. Zhu, Y.-Y. Gui, J.-H. Ye, L. Sun, L.-L. Liao, J. Li, D.-G. Yu*, Visible-Light-Driven Pd-Catalyzed Radical Alkylation of CH Bonds with General Unactivated Alkyl Bromides. Angew. Chem. Int. Ed. 2017, 56, 15683. (Top 2 most accessed papers in November, 2017. Highlighted by X-MOL)

81. J.-H. Ye, L. Zhu, S.-S. Yan, M. Miao, X.-C. Zhang, W.-J. Zhou, J. Li, Y. Lan*, D.-G. Yu*, Radical Trifluoromethylative Dearomatization of Indoles and Furans with CO2. ACS Catal. 2017, 7, 8324. (Equal contribution. Top 6 most read papers in November, 2017.)

82. Y.-Y. Gui, X.-W. Chen, W.-J. Zhou*, D.-G. Yu*, Arylation of Amides and Ureas C(sp3)H Bonds with Aryl Tosylates via in situ Generation from Phenols. Synlett 2017, 28, 2581. (Cover. Invited paper for the issue of C-O activation)

83. L.-L. Liao, Y.-Y. Gui, X.-B. Zhang, G. Shen, H.-D. Liu, W.-J. Zhou, J. Li, D.-G. Yu*, Phosphorylation of Alkenyl and Aryl C─O Bonds via Photoredox/Nickel Dual Catalysis. Org. Lett. 2017, 19, 3735. (Top 2 most read papers in July, 2017)

84. 周文俊*张逸寒曹光梅刘惠东余达刚*钯催化卤代烷烃参与的自由基型转化反应有机化学201737, 1322应邀综述

85. Y.-Y. Gui, W.-J. Zhou, J.-H. Ye, D.-G. Yu*, Photochemical Carboxylation of Activated C(sp3)─H Bonds with CO2. ChemSusChem 2017, 10, 1337. (Equal contribution. Highlight)

 

86. Z. Zhang, T. Ju, J.-H. Ye, D.-G. Yu*, CO2 = CO + O: Redox-neutral Lactamization and Lactonization of C─H Bonds with CO2. Synlett 2017, DOI: 10.1055/s-0036-1588403. (Invited Synpacts paper)

87. Z. Zhang, T. Ju, M. Miao, J.-L. Han, Y.-H. Zhang, X.-Y. Zhu, J.-H. Ye, D.-G. Yu*, Y.-G. Zhi*, Transition-Metal-Free Lactonization of sp2 C─H Bonds with CO2. Org. Lett. 2017. 19, 396. (Equal contribution . Top 3 most read papers in January, 2017)

88. Y.-Y. Gui, L.-L. Liao, L. Sun, Z. Zhang, J.-H. Ye, G. Shen, Z.-P. Lu, W.-J. Zhou, D.-G. Yu*, Coupling of C(sp3)─H Bonds with C(sp2)─O Electrophiles: Mild, General and Selective. Chem. Comm. 2017, 53, 1192.

89. J.-H. Ye, L. Song, W.-J. Zhou, T. Ju, Z.-B. Yin, S.-S. Yan, Z. Zhang, J. Li, D.-G. Yu*, Selective Oxytrifluoromethylation of Allylamines with CO2. Angew. Chem. Int. Ed. 2016, 55, 10022. (Top 4 most read ACIE papers in July, 2016)

90. Z. Zhang, L.-L. Liao, S.-S. Yan, L. Wang, Y.-Q. He, J.-H. Ye, J. Li, Y.-G. Zhi, D.-G. Yu*, Lactamization of sp2 C─H Bonds with CO2: Transition-metal-free and Redox-neutral. Angew. Chem. Int. Ed. 2016, 55, 7068. (扉页文章Highlighted by SynfactsX-MOL以及《有机化学》亮点介绍)

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91. Y.-Y. Gui, L. Sun, Z.-P. Lu, D.-G. Yu*, Photoredox sheds new light on nickel catalysis: from carbon-carbon to carbon-heteroatom bond formation. Org. Chem. Front. 2016, 3, 522. (From themed collection 2015 Emerging Investigators by OCF)

92. X. Wang, D.-G. Yu, F. Glorius*, Cp*Rh(III)-Catalyzed Arylation of sp3 C−H Bonds. Angew. Chem. Int. Ed. 2015, 54, 10280. (Equal contribution)

93. D.-G. Yu, T. Gensch, F. de Azambuja, S. Vásquez-Céspedes, F. Glorius*, Co(III)-Catalyzed C–H Activation/Formal SN-type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation. J. Am. Chem. Soc. 2014, 136, 17722. (Top 3 most read JACS papers in December, 2014).

94. D.-G. Yu, F. de Azambuja, T. Gensch, C. G. Daniliuc, F. Glorius*, The C–H Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIII-Catalysis. Angew. Chem. Int. Ed. 2014, 53, 9650. (Highlighted by Synfacts 2014, 10, 1023)

95. D.-G. Yu, F. de Azambuja, F. Glorius*, Direct Functionalization with Complete and Switchable Positional Control: Free Phenol as A Role Model. Angew. Chem. Int. Ed. 2014, 53, 7710. (Highlight)

96. D.-G. Yu, F. de Azambuja, F. Glorius*, α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles. Angew. Chem. Int. Ed. 2014, 53, 2754. (Top 6 most accessed ACIE paper in Feb. 2014, Highlighted by Synfacts 2014, 10, 567.)

97. D.-G. Yu, S. Luo, F. Zhao, Z.-J. Shi*, Homogeneous Transition-Metal-Catalzyed CO Bond Activation. In Homogeneous Catalysis for Unreactive Bond Activation, Chapter 5, Pages 347439, 2014 (Wiley book).

98. D.-G. Yu, M. Suri, F. Glorius*, RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C−H Amidation and N−N Bond Formation. J. Am. Chem. Soc. 2013, 135, 8802. (equal contribution, most read JACS papers in June, 2013)

99. Z.-J. Shi*, D.-G. Yu, Cross-Coupling Reactions. In Comprehensive Inorganic Chemistry II (Second Edition), Volume 6, Pages 47–77 (2013).

100. D.-G. Yu, X. Wang, R.-Y. Zhu, S. Luo, X.-B. Zhang, B.-Q. Wang, L. Wang, Z.-J. Shi*, Direct Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of Grignard Reagents via Ni, Fe or Co-Catalyzed sp3 CO Bond Activation. J. Am. Chem. Soc. 2012, 134, 14638. (Highlighted by Synfacts 2012, 8, 1358)

101. D.-G. Yu, Z.-J. Shi*, Mutual Activation: Suzuki–Miyaura Coupling through Direct Cleavage of sp2 CO Bond of Naphtholate. Angew. Chem. Int. Ed. 2011, 50, 7097. (Highlighted by Synfacts 2011, 10, 1111)

102. D.-G. Yu, B.-J. Li, S. F. Zheng, B.-T. Guan, B.-Q. Wang, Z.-J. Shi*, Direct Application of Phenolic Salts in Nickel-Catalyzed Cross-Coupling with Aryl Grignard Reagents. Angew. Chem. Int. Ed. 2010, 49, 4566. (Hot paper, the frontpieces of Communications, highlighted by ChemistryViews, Synfacts 2010, 9, 1051以及《有机化学》亮点介绍)

103. D.-G. Yu, B.-J. Li, Z.-J. Shi*, Exploration of new CO electrophiles in cross-coupling reactions. Acc. Chem. Res. 2010, 43, 1486. (Invited account. Top ten most-accessed articles of Acc. Chem. Res. in 2010)

104. C.-L. Sun, H. Li, D.-G. Yu, M. Yu, X. Zhou, X.-Y. Lu, K. Huang, S.-F. Zheng, B.-J. Li, Z.-J. Shi*, An efficient organocatalytic method for constructing biaryls through aromatic CH activation. Nature Chem. 2010, 2, 1044. (C.-L. Sun, H. Li, and D.-G. Yu performed the experiments and analysed the data and contributed equally to this work, highlighted by Nature Chem., Nature China and Synform)

105. S. Luo, D.-G. Yu, R.-Y. Zhu, X. Wang, L. Wang, Z.-J. Shi*, Fe-promoted cross coupling of homobenzylic methyl ethers with Grignard reagents via sp3 C–O bond cleavage. Chem. Comm. 2013. 49, 7794. (equal contribution)

106. D.-G. Yu, M. Yu, B.-T. Guan, B.-J. Li, Y. Zheng, Z.-H. Wu, Z.-J. Shi*, CarbonCarbon Formation via Ni-Catalyzed Suzuki-Miyaura Coupling through CCN Bond Cleavage of Aryl Nitrile. Org. Lett. 2009, 11, 3374. (Highlighted by Synfacts 2009, 11, 1255)

107. 施章杰* 余达刚,合成化学中的焊接技术。科技导报2010 28 29。(综述)

108. D.-G. Yu, B.-J. Li, Z.-J. Shi*, Challenges in C-C Bond Formation through Direct Transformations of sp2 CH Bonds. Tetrahedron 2012, 68, 5130. (Invited account in special issue for Tetrahedron Young Investigator Award 2012 Advances in Metal-Mediated Organic Synthesis Zhang-Jie Shi. Cover. Top 3 hottest paper in 2012)

109. Z.-C. Cao, D.-G. Yu, R.-Y. Zhu, J.-B. Wei, Z.-J. Shi*, Direct Cross Coupling of Benzyl Alcohols to Construct Diarylmethanes via Palladium Catalysis. Chem. Comm. 2015, 51, 2683.

Graphical abstract: Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis

110. F. Zhao, D.-G. Yu, R.-Y. Zhu, Z.-F. Xi*, Z.-J. Shi*, Cross-Coupling of Aryl/Alkenyl Silyl Ether with Grignard Reagents through Nickel-Catalyzed CO Bonds Activation. Chem. Lett. 2011, 40, 1001. (Invited research paper in Celebration for the 2010 Nobel Prize in Chemistry)

111. B.-J. Li, D.-G. Yu, C.-L. Sun, Z.-J. Shi*, Activation of “Inert” Alkenyl/Aryl CO Bond and its Application in Cross-Coupling Reactions. Chem. Eur. J. 2011, 17, 1728. (Review)

112. K. Huang, D.-G. Yu, S.-F. Zheng, Z.-H. Wu, L. Xu, B.-Q. Wang, Z.-J. Shi*, Direct Borylation of Aryl and Vinyl Carbamates via Ni-Catalyzed CO Activation. Chem. Eur. J. 2010, 17, 786.

113. H. Wang, B. Beiring, D.-G. Yu, K. Collins, F. Glorius, [3]Dendralene Synthesis: Rhodium(III)-Catalyzed Alkenyl C–H Activation and Coupling Reaction with Allenyl Carbinol Carbonate, Angew. Chem. Int. Ed. 2013, 52, 12430.

114. F. Zhao, Y.-F. Zhang, J. Wen, D.-G. Yu, J.-B. Wei, Z.-F. Xi*, Z.-J. Shi*, Programmed Selective sp2 C–O Bond Activation toward Multiarylated Benzenes. Org. Lett. 2013, 15, 3230.

115. K. Huang, G. Li, W.-P. Huang, D.-G. Yu, Z.-J. Shi*, Arylation of α-pivaloxyl Ketones with Arylboronic Reagents via Ni-catalyzed sp3 CO Activation. Chem. Commun. 2011, 47, 7224.

116. H. Li, C.-L. Sun, M. Yu, D.-G. Yu, B.-J. Li, Z.-J. Shi*, The Catalytic Ability of Various Transition Metals in the Direct Functionalization of Aromatic C–H Bonds. Chem. Eur. J. 2011, 17, 3593.

117. C.-L. Sun, N. Liu, B.-J. Li, D.-G. Yu, Y. Wang, Z.-J. Shi*, Pd-Catalyzed C-H Functionalizations of O-Methyl Oximes with Arylboronic Acids. Org. Lett. 2010, 12, 184.

118. B.-T. Guan, X.-Y. Lu, Y. Zheng, D.-G. Yu, T. Wu, K.-L. Li, B.-J. Li, Z.-J. Shi*, Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions. Org. Lett. 2010, 12, 396. (Highlighted by Synfacts 2010, 4, 0455)

119. B.-T. Guan, Y. Wang, B.-J. Li, D.-G. Yu, Z.-J. Shi*, Biaryl Construction via Ni-Catalyzed CO Activation of Aryl Carboxylates. J. Am. Chem. Soc. 2008, 130, 14468. (Highlighted by Angew. Chem. Int. Ed2009, 48, 3569)

 

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